1st Appearance - Villains

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THE VILLAINS

.

A

Abomination - Tales to Astonish #90 (1967)

Absorbing Man – Journey Into Mystery #114 (1965)

Amazo – Brave and the Bold (JLA) #30 (1960)

Apocalypse - X-Factor #5 (1986)

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B

Bane – Batman: Vengeance of Bane #1 (1993)

Baron Zemo – Avengers #6 (1964)

Beyonder – Secret Wars #1 (1984)

Bizarro – Superboy #68 (1958)

Black Adam (Fawcett/DC) – Marvel Family #1 (1945)

Blob – X-men #3 (1964)

Brainiac – Action Comics #242 (1958)

Brotherhood of Evil Mutants – X-men #4 (1964)

Bullseye (II) – Daredevil #131 (1976)

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C

Carnage – Amazing Spider-man #361 (1st Full App.) (1993)

Catwoman -  1st Full App. as Catwoman in Costume Batman #3 (1940)

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D

Darkseid – Superman’s Pal Jimmy Olsen #134 (1970)

Deadpool – New Mutants #98 (1991)

Deathlok – Astonishing Tales #25 (1974)

Deathstroke – New Teen Titans #2 (1980)

Doctor Doom – Fantastic Four #5 (1962)

Doc Octopus – Amazing Spiderman #3 (1963)

Doomsday – 1st Full App. Superman: The Man of Steel #18 (1993)

Doctor Light – Justice League of America #12 (1962)

.

E

Electro – Amazing Spiderman #9 (1964)

Evil Ernie – Evil Ernie #1 (1991)

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F

.

G

Galactus – Cameo Fantastic Four #48 1st Full App. Fantastic Four #49 (1966)

Gladiator (Melvin Potts) – Daredevil #18 (1966)

Green Goblin – (Norman Osborn) Amazing Spiderman #14 (1964)

.

H

Harley Quinn -  Mad Love #1 (1994)

High Evolutionary – Thor #134 (1966)

Hobgoblin – Amazing Spiderman #238 (1983)

Hood (Parker Robbins) – The Hood #1 (2002)

Hugo Strange – Detective Comics #36 (1940)

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J

Jigsaw (Punisher)- Amazing Spiderman #162 (1976)

Joker – Batman #1 (1940)

Juggernaut – X-men #12 (1965)

.

K

KGBeast – Batman #417 (1988)

Killraven – Amazing Adventures #18 (1973)

Kingpin – Amazing Spiderman #50 (1967)

Kraven the Hunter – Amazing Spiderman #15 (1964)

.

L

Lady Death – Evil Ernie #1 (1991)

Lady Deathstrike – Alpha Flight #33 (1986)

Leader – Tales to Astonish #62 (1965)

Legion (David Haller) – New Mutants #25 (1985)

Lex Luthor – Action Comics #23 (1940)

Lizard – Amazing Spiderman #6 (1963)

Lobo – Omega Men #3 (1983)

.

M

Mad Hatter – Detective Comics #230 (1956)

Magneto – X-men #1 (1963)

Man-Bat – Detective Comics #400 (1970)

Marauders – Uncanny X-men #210 (1986)

Marvel Zombies - Ultimate Fantastic Four #21 (2005)

Mephisto – Silver Surfer Vol. 1 #3 (1968)

Mimic – X-men #19 (1966)

Mirror Master – The Flash #105 (1959)

Mister Sinister – X-men #221 (1989)

Modok – Tales of Suspense #94 (1967)

Mojo -  Longshot #3 (1985)

Molecule Man – Fantastic Four #20 (1963)

Mole Man – Fantastic Four #1 (1961)

Molten Man – Amazing Spiderman #28 (1965)

Mr. Freeze – Batman #121 (1959)

Mxyztplk – Superman #30 (1944)

Mysterio – Amazing Spiderman #13 (1964)

.

N

Nitro – Captain Marvel #34 (1974)

Nuke – Daredevil #232 (1985)

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O

Omega Red – X-men #18 Vol 2 (1994)

Onslaught – X-Man #15 (1996)

Owl – Daredevil #3, Vol 1 (1964)

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P

Penguin – Detective Comics #58 (1941)

Phalanx - Uncanny X-men #311 (1994)

Poison Ivy - Batman #181 (1966)

.

R

Ra’s al Ghul – Batman #232 (1971)

Red Skull – Captain America Comics #7 (1941)

Rhino – Amazing Spiderman #41 (1966)

Riddler – Detective Comics #140 (1948) Silver Age App. Batman #171 (1965)

.

S

Sabretooth – Iron Fist #14 (1977)

Sandman – Amazing Spiderman #4 (1963)

Scarecrow – World’s Finest Comics #3 (1941)

Scorpion – Amazing Spiderman #20 (1964)

Sentinels – X-men #14 (1965)

Sinestro – Green Lantern #7 (1961)

Son of Satan – 1st Full app. Ghost Rider #2 (1973)

Spiral – Longshot #1 (1985)

Stilt-Man – Daredevil #8 (1965)

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T

Talia (Ra’s al Ghul’s Daughter) – Detective Comics #411 (1971)

Taskmaster – Avengers #195 (Cameo) #196 (1st Full App.) (1980)

Thanos – Iron Man #55 (1973)

Thunderbolts – Incredible Hulk #449 (1997)

Toad – X-men #4 (1964)

Two Face – Detective Comics #66 (1942) Silver Age App. Batman #234 (1971)

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U

Ultron - Avengers #54 (1968)

Unus the Untouchable – (Uncanny) X-Men #8 (1963)

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V

Venom – (cameos) Amazing Spiderman #298-299 – #300 (1st Full Appearance) (1988)

Vixen – Action Comics #521 (1981)

Vulture – Amazing Spiderman #2 (1963)

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W

Wendigo – Incredible Hulk #162 (1973)

Whiplash (Iron Man) - Tales of Suspense #97 (1968)

White Queen (Emma Frost) – X-men #129 (1980)

.

Z

Zsasz (Victor) – Batman: Shadow of the Bat #1 (1992)